- Ethanol Dehydration: Removal of water from ethanol using molecular sieve dehydration breaking the ethanol-water azeotrope in the process
- Glycerin Dehydration: Removal of water from glycerin using flash evaporation
- Isopropyl Alcohol Dehydration: Removal of water from IPA using molecular sieve dehydration breaking the IPA-water azeotrope in the process
- Methanol Dehydration: Removal of water from methanol using molecular sieve dehydration (can be an economical alternative to distillation)
- Methanol Recovery from Biodiesel: Removal and recovery of methanol from Biodiesel using flash evaporation
- Vacuum Distillation: Distillation at vacuum allows for products to be vaporized at lower temperatures so components with high bubble points can be distilled more economically. Vacuum distillation can also be used to “break” an azeotrope allowing for higher percent yields.
Methanol Recovery Systems for the Biodiesel Industry
Most biodiesel in the USA is made by reacting vegetable (Soy) oils with methanol in the presence of a catalyst by a chemical process known as transesterification. The reaction process forms two products: methyl ester (which is the bio-diesel) and glycerol. To force the reaction to completion, an excess amount (20-100% more methanol than actually required for reaction) of methanol is used. The two products are separated by decanting or centrifuge, and the excess (un-reacted) methanol is divided between the two products: approximately 40% with the biodiesel, and 60% with the glycerol.
Methanol Recovery from both the biodiesel and glycerol products is imperative to the economics of any biodiesel production facility. The preferred result is to recover the methanol in a form for re-use in production to reduce the overall methanol costs. There are a couple steps involved: methanol extraction from biodiesel (or glycerol), and recovery of the methanol.
There are several different methods of extracting methanol from biodiesel and glycerin: vacuum flash evaporation, distillation, and water washing. However, at low concentrations, methanol/biodiesel and methanol/glycerin mixtures are non-ideal, meaning due to molecular level interactions, they do not behave in the same way as typical ideal solutions do. If a simple flash evaporation operation is performed based solely on the vapor pressure of methanol, only a portion of the methanol will be removed which means more methanol may remain in the biodiesel than desired. To remove the final amounts of methanol to the low levels of ASTM requirements is more complex.
Biodiesel water washing to remove the total amount of methanol from biodiesel generally is a lower equipment cost method of extraction, however the separation of methanol from the resulting methanol-water mix becomes expensive.
Distillation of methanol from biodiesel can be performed in a single column, however the column is relatively complex in design, control and operation, and more expensive.
To remove the final amounts of methanol to the lower level ASTM requirements is more complex, so Wintek’s Flash Tower systems for methanol extraction and recovery includes several unit operations (flash vacuum evaporation being one) to assure removal down to or below your target level. They are designed for continuous operation, easy for operators to understand and control, and typically lower cost than distillation columns. Our systems are provided complete with flash towers (1, 2, or 3-stage), vacuum condensers, transfer pumps, flow meters, rugged process vacuum pump systems and PLC control panel. The number of stages of flash towers, and final cost, is dependent upon:
- The amount of excess methanol in the biodiesel (or glycerol)
- The residual methanol concentration allowed in the product
- Utilities available (heating and cooling)
- And materials of construction.
Wintek’s designs are highly reliable, simple to operate and control, low maintenance, and cost effective. Each Methanol Recovery System is custom designed to meet the customer’s requirements.
- 99+% Methanol Recovery (of excess methanol)
- High Reliability
- Easy to understand
- Easy to operate and control
- Low maintenance